.Net has several methods of serialization and sometimes it causes a lot of confusion even for experienced programmers. I believe the best article to describe the different methods is Aaron Skonnard’s Serialization in Windows Communication Foundation(MSDN Magazine > Issues > 2006 > August) (by some reason it’s not highly rated by Google and other articles are coming first for Serialization related requests)
There is also a brief comparison table in StackOverflow What are the differences between the XmlSerializer and BinaryFormatter.
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