I am including here the objectives and the materials I am using to prepare.

Installing and Configuring TFS

Objective Materials
Install TFS TFS Installation Guide
Configure Application Tier Managing Server Configuration
Migrate and Upgrade TFS TFS Upgrade Guide
http://msdn.microsoft.com/en-us/library/ms404851.aspx
Install and Configure Lab Management MSDN Lab Management Info
Install and Configure Build Controllers and Agents Build Controller Info
Build Agent Info

 

Managing TFS

Objective Materials
Manage Team Project Collections http://msdn.microsoft.com/en-us/library/dd236915.aspx
Configure for backup and recovery http://msdn.microsoft.com/en-us/library/bb552295.aspx
Monitor server health and performance http://msdn.microsoft.com/en-us/library/ms252442(v=VS.90).aspx
Administer TFS application tier http://msdn.microsoft.com/en-us/library/bb385832.aspx#Administering
Manage Reporting for TFS http://msdn.microsoft.com/en-us/library/dd386355.aspx
http://msdn.microsoft.com/en-us/library/ee712737.aspx
http://msdn.microsoft.com/en-us/library/ee712730.aspx
Setup automated functional and UI Tests http://msdn.microsoft.com/en-us/library/dd286729.aspx

 

Customizing TFS for Team Use

Objective Materials
Configure a team build definition http://msdn.microsoft.com/en-us/library/ms181715.aspx
Configure and execute a build http://msdn.microsoft.com/en-us/library/ms181722.aspx
Modify a process template http://msdn.microsoft.com/en-us/library/ms243782.aspx
Configure a team project http://msdn.microsoft.com/en-us/library/dd286619.aspx
Apply work item customizations http://msdn.microsoft.com/en-us/library/dd286632.aspx#Customize
Create WIQL queries http://msdn.microsoft.com/en-us/library/bb130347.aspx
Configure client connectivity to TFS Using Visual Studio 2010
Using Visual Studio 2008

Administering Version Control

Objective Materials
Create and manage workspaces http://msdn.microsoft.com/en-us/library/ms181383.aspx
Configure shelvesets http://msdn.microsoft.com/en-us/library/ms181403.aspx
Branch and merge source artifacts http://msdn.microsoft.com/en-us/library/ms181423.aspx
Configure version control proxy http://msdn.microsoft.com/en-us/library/ms245478.aspx
Configure team project version control settings http://msdn.microsoft.com/en-us/library/dd551469.aspx