Here are a few goodies I came across for Office Word 2007...
Want help getting started with Word 2007? Add the "Getting Started" ribbon tab inside of Word: http://blogs.msdn.com/microsoft_office_word/archive/2007/07/05/helpful-new-word-ribbon-tab.aspx
Having trouble with the new Word ribbon (menu) system? Use this interactive guide to help with the transition from the previous menu system to the current ribbon system: http://office.microsoft.com/en-us/word/HA100744321033.aspx
What to save Office documents in the PDF format? Get the free plug-in: http://www.microsoft.com/downloads/details.aspx?familyid=4D951911-3E7E-4AE6-B059-A2E79ED87041&displaylang=en