Check this out, the VB team has released a 24x18" poster of the default keyboard mappings in VS 2005. Its available in color for the feng shui conscious coder or black and white for the dungeon dwelling coder. I printed the b/w version on a laser printer (landscape) and though the text is kind of small, it's still very usable. On the other hand, another option is a quick trip to Kinko's (or your favorite printer) armed with the PDF on a jump drive and get it printed full size in color or b/w.
This will definately be making its way in to the materials we distribute at our VB training classes.